Nonlinear characterization of Ge₂₈Sb₁₂Se₆₀ bulk and waveguide devices.

Single-mode Ge₂₈Sb₁₂Se₆₀ strip waveguides, fabricated with thermal evaporation and lift-off, were demonstrated at 1.03 µm. The linear and nonlinear optical properties of these waveguides were shown to be similar to bulk samples, with differences attributed to small variations in composition of ~4 atomic % or less. From z-scan measurements at 1.03 µm using circularly polarized, ~200 fs pulses at 374 kHz, Ge₂₈Sb₁₂Se₆₀ was found to have a nonlinear refractive index ~130 x fused silica and a two-photon absorption coefficient of 3.5 cm/GW. Given the large two-photon absorption coefficient, this material shows promise for optical limiting applications at 1 µm.